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http://acervodigital.unesp.br/handle/11449/68557
- Title:
- Densification of Mn-doped tin oxide films by conventional heating and microwave heating treatment
- Universidade Estadual Paulista (UNESP)
- Université de Bourgogne
- Université Paris-Sud
- 0281-1847
- Mn(II) doped SnO2 thin films used for shielding fluoride glasses against corrosion were investigated by x-ray absorption spectroscopy (EXAFS and XANE)S at the Sn and Mn K-edges. The effect of firing treatment on the densification of the films was studied. It has been evidenced a partial change of Mn valence from 2.3 to 2.6 upon heating which is attributed to a change of ratios of two Mn sites: grafted divalent Mn ions at the surface of SnO 2 nanocrystallites and trivalent Mn ions embedded into a substitutional solid solution with Sn. © Physica Scripta 2005.
- 1-Dec-2005
- Physica Scripta T, v. T115, p. 291-293.
- 291-293
- Densification
- Extended X ray absorption fine structure spectroscopy
- Manganese
- Microwave heating
- Tin dioxide
- Fluoride glasses
- Tin oxide films
- Oxide films
- http://dx.doi.org/10.1238/Physica.Topical.115a00291
- Acesso restrito
- outro
- http://repositorio.unesp.br/handle/11449/68557
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