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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/135841
Title: 
Chemoselective condensation of β-naphthol, dimethyl malonate, and aromatic aldehydes promoted by niobium pentachloride
Author(s): 
Institution: 
Universidade Estadual Paulista (UNESP)
ISSN: 
0039-7911
Abstract: 
A multicomponent reaction of β-naphthol, dimethyl malonate, and aromatic aldehydes in the presence of NbCl5 as promoter is described. Under similar conditions, aromatic aldehydes with different substituents exhibited different behaviors than β-naphthol and dimethyl malonate. In these MCRs, 4-aryl-3,4-dihydrobenzo[f]coumarins are obtained as the major products (41–93%) and 14-aryl-14H-dibenzo[a,j]xanthenes as the minor products (1–38%).
Issue Date: 
2015
Citation: 
Synthetic Communications, v. 45, n. 9, p. 1114-1126, 2015.
Time Duration: 
1114-1126
Keywords: 
  • 4-Aryl-3,4-dihydrobenzo[f]coumarins
  • Chemoselective
  • Lewis acid
  • Multicomponent reactions
  • Niobium pentachloride
Source: 
http://dx.doi.org/10.1080/00397911.2014.999341
URI: 
Access Rights: 
Acesso restrito
Type: 
outro
Source:
http://repositorio.unesp.br/handle/11449/135841
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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