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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/34007
Title: 
Photoluminescence in disordered Zn2TiO4
Author(s): 
Institution: 
  • Universidade Federal da Paraíba (UFPB)
  • Universidade Estadual Paulista (UNESP)
  • Universidade Federal de São Carlos (UFSCar)
ISSN: 
0022-4596
Abstract: 
In this work, the polymeric precursor method Was used to obtain disordered Zn2TiO4 powders, either Undoped or doped with Sn4+, Cr3+ and V5+, to be applied its photoluininescent material. The characterization was undertaken by means of thermal analysis (TG and DTA), X-ray diffraction (XRD), infrared spectroscopy (IR) and photoluminescence (PL). Previous works stated that titanate octahedra containing a short Ti-O distance show efficient luminescence at roorn temperature if these octahedra are isolated from each other. In the present work, the phenomenon was observed in condensed octahedra, sharing edges. The room temperature PL noticed in undoped Zn2TiO4 had its intensity increased by the dopant addition-the increase was of about 300% for V5+ doping 400% for Cr3+ and 800% for Sn4+. (c) 2005 Elsevier B.V. All rights reserved.
Issue Date: 
1-Apr-2006
Citation: 
Journal of Solid State Chemistry. San Diego: Academic Press Inc. Elsevier B.V., v. 179, n. 4, p. 985-992, 2006.
Time Duration: 
985-992
Publisher: 
Elsevier B.V.
Keywords: 
  • disordered materials
  • pechini
  • luminescence
  • titanate
  • spinel
Source: 
http://dx.doi.org/10.1016/j.jssc.2005.12.018
URI: 
Access Rights: 
Acesso restrito
Type: 
outro
Source:
http://repositorio.unesp.br/handle/11449/34007
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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