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- Structural organization and thermal properties of the Sb2O3-SbPO4 glass system
- Universidade Estadual Paulista (UNESP)
- Univ Rennes 1
- Ctr Univ Paris Sud
- Univ Munster
- The structural organization of Sb2O3-SbPO4 glasses has been studied by FTIR, Raman, P-31 MAS and spin echo NMR, Mossbauer and X-ray absorption spectroscopy (EXAFS and XANES at K and L-3,L-1-Sb edges). The combined results can be explained in terms of two potential mechanisms describing the change of the Sb(m) local environment upon incorporation of Q((4))-type phosphate. The formation of the latter species requires anionic compensation that may be adjusted by (a) formation of non bridging oxygen or (b) formation of SbO4E- groups (E = non-bonding electron pair). The second model is favored.
- Journal of Materials Chemistry. Cambridge: Royal Soc Chemistry, v. 14, n. 23, p. 3398-3405, 2004.
- Royal Soc Chemistry
- Acesso restrito
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