Pyrazolyl coordination polymers of cadmium(II)

da Silva, P. B.; Frem, RCG; Netto, AVG; Mauro, Antonio Eduardo; Ferreira, J. G.; Santos, RHA

Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/38305

Title:

Pyrazolyl coordination polymers of cadmium(II)

Author(s):

Institution:

Universidade Estadual Paulista (UNESP)
Universidade de São Paulo (USP)

ISSN:

1387-7003

Abstract:

The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. Both complexes exhibited chain structures made by linear arrays of Cd(II) bridged by chloro (1) or inversely related 1,3-SCN groups (2) and the pyrazole ligands at the apical. sites. Intermolecular hydrogen bonds and another non-covalent interactions are responsible for the self-assembly of linear chains into 2D networks. (c) 2005 Elsevier B.V. All rights reserved.

Issue Date:

1-Feb-2006

Citation:

Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 9, n. 2, p. 235-238, 2006.

Time Duration:

235-238

Publisher:

Elsevier B.V.

Keywords:

coordination polymers
pyrazole
cadmium(II)
thiocyanate
non-covalent interactions
self-assembly

Source:

http://dx.doi.org/10.1016/j.inoche.2005.11.015

URI:

Access Rights:

Acesso restrito

Type:

outro

Source:

http://repositorio.unesp.br/handle/11449/38305

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