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- Título:
- Ionic medium effects on equilibrium constants .1. Proton, copper(II), cadmium(II), lead(II) and acetate activity coefficients in aqueous solution
- Universidade Estadual Paulista (UNESP)
- UNIV FED MARAHAO
- 0039-9140
- The molar single ion activity coefficients associated with hydrogen, copper(II), cadmium(II) and lead(II) ions were determined at 25 degrees C and ionic strengths between 0.100 and 3.00 M (NaClO4), whereas for acetate the ionic strengths were fixed between 0.300 and 2.00 M, held with the same inert electrolyte. The investigation was carried out potentiometrically by using proton-sensitive glass, copper, cadmium and lead ion-selective electrodes and a second-class Hg\Hg-2(CH3COO)(2) electrode. It was found that the activity coefficients of these ions (y(i)) can be assessed through the following empirical equations:log y(H) = -0.542I(0.5) + 0.451I; log y(Cu) = -1.249I(0.5) + 0.912I; log y(Cd) = -0.829I(0.5) + 0.448I(1.5);log y(Pb) = -0.404I(0.5) + 0.117I(2); and log y(Ac) = 0.0370I .
- 1-Out-1996
- Talanta. Amsterdam: Elsevier B.V., v. 43, n. 10, p. 1689-1695, 1996.
- 1689-1695
- Elsevier B.V.
- ionic activity coefficients
- ionic medium effects
- http://dx.doi.org/10.1016/0039-9140(96)01944-3
- Acesso restrito
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- http://repositorio.unesp.br/handle/11449/39054
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