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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/116172
Title: 
Sugars Electrooxidation at Glassy Carbon Electrode Decorate with Multi-Walled Carbon Nanotubes with Nickel Oxy-Hydroxide
Author(s): 
Institution: 
Universidade Estadual Paulista (UNESP)
ISSN: 
1452-3981
Sponsorship: 
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Sponsorship Process Number: 
  • FAPESP: 11/19289-5
  • FAPESP: 12/00258-5
  • FAPESP: 11/20416-1
Abstract: 
The glassy carbon electrode modified with carbon nanotubes decorated with nickel oxy-hydroxide (GC/MWCNT/NiOOH) was used to studied electro-oxidation of glucose, galactose, xylose, arabinose and mannose in alkaline medium. Kinetic parameters such as, charge-transfer coefficient, electrocatalytic rate constant and diffusion coefficient were determined for sugars. Galactose exhibited a higher charge-transfer coefficient (0.37) with a diffusion coefficient of 1.3x10(-6) cm(2) s(-1) and showed the higher electrocatalytic rate constant of 2.1x10(4) L mol(-1) s(-1). The modified electrode exhibited a linear response to sugars concentration in the range around of 2.5x10(-4) mol L-1 to 5.6x10(-3) mol L-1 and limits of detection around of 1.9x10(-4) mol L-1 -4.3x10(-4) mol L-1.
Issue Date: 
1-Dec-2014
Citation: 
International Journal Of Electrochemical Science. Belgrade: Esg, v. 9, n. 12, p. 7746-7762, 2014.
Time Duration: 
7746-7762
Publisher: 
Esg
Keywords: 
  • Electrocatalytic rate constant of sugars
  • Kinetic parameters
  • Nickel oxy-hydroxide
  • Carbon nanotubes
  • Chemically modified electrodes
Source: 
http://connection.ebscohost.com/c/articles/99328080/sugars-electrooxidation-glassy-carbon-electrode-decorate-multi-walled-carbon-nanotubes-nickel-oxy-hydroxide
URI: 
Access Rights: 
Acesso restrito
Type: 
outro
Source:
http://repositorio.unesp.br/handle/11449/116172
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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