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http://acervodigital.unesp.br/handle/11449/116809- Title:
- Laser-flash photolysis of alpha-brominated o-xylenes
- Universidade de São Paulo (USP)
- Universidade Estadual Paulista (UNESP)
- 1010-6030
- The flash photolysis (lambda = 266 nm) of four alpha -brominated omicron -xylenes in apolar solvents gives two transients characterized, depending on parent compound substitution, as either monoradicals or carbenes, and quinodimethanes. alpha -Bromomethylbenzyl radical is characterized and the novel species alpha,alpha'-dibromo-omicron -xylylene and omicron-(alpha,alpha -dibromomethyl)benzyl carbene are described for the first time. (C) 2001 Elsevier Science B.V. All rights reserved.
- 13-Apr-2001
- Journal Of Photochemistry And Photobiology A-chemistry. Lausanne: Elsevier Science Sa, v. 140, n. 1, p. 1-5, 2001.
- 1-5
- Elsevier B.V.
- flash-photolysis
- quinodimethanes
- photohomolysis
- monoradicals
- carbenes
- alpha-brominated o-xylenes
- http://dx.doi.org/10.1016/S1010-6030(01)00384-7
- Acesso restrito
- outro
- http://repositorio.unesp.br/handle/11449/116809
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