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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/123565
Title: 
Asymmetric and Symmetric Triazenido Cyclopalladated Complexes: Synthesis, Structural Analysis and DFT Calculations
Author(s): 
Institution: 
  • Universidade de Passo Fundo (UPF)
  • Universidade Estadual Paulista (UNESP)
  • Universidade Federal de Alfenas (UNIFAL)
  • Universidade Federal de Santa Maria (UFSM)
ISSN: 
0022-2860
Abstract: 
The reaction of [Pd{dmba}(l-N3)]2 (dmba = N,N-dimethylbenzylamine) with 1-(2-fluorophenyl)-3-(4- nitrophenyl)triazenido (L1 ) or 1,3-bis(4-nitrophenyl)triazenido (L2 ) anions, in methanol, and subsequent treatment with pyridine (py) allows the preparation of the corresponding cyclopalladated compounds [Pd(dmba)(L1 )(py)] (1) and [Pd(dmba)(L2 )(py)]py (2). The acentric mononuclear entities of (1) and (2) are connected by weak intermolecular non-classical CAHC hydrogen bonds, which results in 2-D arrangements by translation, along the [1 0 0] and [0 01] crystallographic directions, respectively.
Issue Date: 
2014
Citation: 
Journal of Molecular Structure, v. 1083, p. 311-318, 2014.
Time Duration: 
311-318
Keywords: 
  • triazenido ligand
  • supramolecular arrangement
  • cyclopalladated complex
  • Non-classical CH C hydrogen bond
URI: 
Access Rights: 
Acesso restrito
Type: 
outro
Source:
http://repositorio.unesp.br/handle/11449/123565
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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