Thermal decomposition of palladium(II) pyrazolyl complexes. Part I

Netto, AVG; Takahashi, P. M.; Frem, RCG; Mauro, Antonio Eduardo; Zorel, H. E.

Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/32709

Title:

Thermal decomposition of palladium(II) pyrazolyl complexes. Part I

Author(s):

Institution:

Universidade Estadual Paulista (UNESP)
Fac Intergradas Catolicas Palmas

ISSN:

0165-2370

Abstract:

The thermal behavior of simple and mixed pyrazolyl complexes [PdCl2(phmPz)(2)] (1),[Pd(N-3)(2)(phmPz)(2)] (2), [Pd(SCN)(2)(phmPz)(2)] (3), and [Pd(N-3)(SCN)(phmPz)(2)] (4) (phmPz: 1-phenyl-3-methylpyrazole) has been investigated by means of thermogravimetry (TG) and differential thermal analysis (DTA). From the initial decomposition temperatures, the thermal stability of the complexes can be ordered in the sequence: 4 < 2 < 3 < 1. The final products of the thermal decompositions were characterized as metallic palladium (Pd-0). (C) 2004 Elsevier B.V. All rights reserved.

Issue Date:

1-Aug-2004

Citation:

Journal of Analytical and Applied Pyrolysis. Amsterdam: Elsevier B.V., v. 72, n. 1, p. 183-189, 2004.

Time Duration:

183-189

Publisher:

Elsevier B.V.

Keywords:

palladium
pyrazoles
IR and NMR spectroscopy
thermal analysis

Source:

http://dx.doi.org/10.1016/j.jaap.2004.03.010

URI:

Access Rights:

Acesso restrito

Type:

outro

Source:

http://repositorio.unesp.br/handle/11449/32709

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