Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)2] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-Bis(diphenylphosphino)methane and dppb=1,4-Bis(diphenylphosphino)butane]

Batista, Alzir A.; Pereira, Cid; Wohnrath, Karen; Queiroz, Salete L.; De A. Santos, Regina H.; Do P. Gambardella, Maria Teresa

Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/65794

Title:

Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)2] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-Bis(diphenylphosphino)methane and dppb=1,4-Bis(diphenylphosphino)butane]

Author(s):

Institution:

Universidade Federal de São Carlos (UFSCar)
Universidade Estadual Paulista (UNESP)
Universidade de São Paulo (USP)

ISSN:

0277-5387

Abstract:

The fac-[RuCl3(NO)(dppm)] (1) and cis-[RuCl2(dppm)2] (2) complexes were obtained with co-crystallization in the solid state from the reaction of RuCl3(NO) with the diphosphine in dichloromethane. mer-[RuCl3(NO)(dppb)] (3) was obtained from [RuCl3(dppb)(H2O)] by bubbling NO for 30 min in the same solvent. The crystal and molecular structures of these three compounds have been determined from X-ray studies. © Elsevier Science Ltd.

Issue Date:

11-Jun-1999

Citation:

Polyhedron, v. 18, n. 15, p. 2079-2083, 1999.

Time Duration:

2079-2083

Keywords:

Complexes, Biphosphines
Isomerism
Nitrosyl
Ruthenium
X-ray structure

Source:

http://dx.doi.org/10.1016/S0277-5387(99)00084-4

URI:

Access Rights:

Acesso restrito

Type:

outro

Source:

http://repositorio.unesp.br/handle/11449/65794

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