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http://acervodigital.unesp.br/handle/11449/76014- Title:
- Why silver deposition is so fast: Solving the enigma of metal deposition
- Ulm University
- Universidade Estadual Paulista (UNESP)
- Lehrstuhl für Theoretische Chemie
- Universidad Nacional Del Litoral
- Universidad Nacional de Cõrdoba
- 1433-7851
- 1521-3773
- Deutsche Forschungsgemeinschaft (DFG)
- DFG: Schm 344/34-1,2
- DFG: FOR 1376
- A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- 22-Jul-2013
- Angewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.
- 7883-7885
- corrosion
- metal deposition
- theoretical electrochemistry
- Electrochemical reactions
- MD simulation
- Metal deposition
- Perfect matches
- Silver deposition
- Solvation energy
- Strong interaction
- Catalysis
- Chemistry
- Corrosion
- Deposition
- http://dx.doi.org/10.1002/anie.201301998
- Acesso restrito
- outro
- http://repositorio.unesp.br/handle/11449/76014
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