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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/110
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dc.contributor.authorGuerrero, Palimclo G.-
dc.contributor.authorDabdoub, Miguel J.-
dc.contributor.authorBaroni, Adriano C. M.-
dc.date.accessioned2014-05-20T13:12:07Z-
dc.date.accessioned2016-10-25T16:32:26Z-
dc.date.available2014-05-20T13:12:07Z-
dc.date.available2016-10-25T16:32:26Z-
dc.date.issued2008-06-09-
dc.identifierhttp://dx.doi.org/10.1016/j.tetlet.2008.04.072-
dc.identifier.citationTetrahedron Letters. Oxford: Pergamon-Elsevier B.V. Ltd, v. 49, n. 24, p. 3872-3876, 2008.-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/11449/110-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/110-
dc.description.abstractThe hydroalumination of butylseleno acetylenes with DIBAL-H followed by addition of n-butyllithium generated in situ the (Z)-butylseleno vinyl alanates intermediates which were captured with C(4)H(9)TeBr furnishing the (E)-telluro(seleno)ketene acetals exclusively. The isomers with opposite stereochemistry (Z)-telluro(seleno)ketene acetals were obtained by the reduction of phenylseleno acetylenes with lithium di-(isobutyl)-n-butyl aluminate hydride (Zweifel's reagent) followed by reaction of (E)-phenylseleno vinyl alanates intermediates with C(4)H(9)TeBr. (c) 2008 Elsevier Ltd. All rights reserved.en
dc.format.extent3872-3876-
dc.language.isoeng-
dc.publisherPergamon-Elsevier B.V. Ltd-
dc.sourceWeb of Science-
dc.titleHydroalumination of seleno acetylenes: a versatile generation and reactions of alpha-aluminate vinyl selenide intermediates in the highly regio and stereoselective synthesis of telluro(seleno)ketene acetalsen
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.contributor.institutionUniversidade Federal de Mato Grosso do Sul (UFMS)-
dc.description.affiliationUNESP, Lab Quim Organ, BR-11900000 Registro, SP, Brazil-
dc.description.affiliationUSP, Lab Compostos Organocalcogenios, BR-14500000 Ribeirao Preto, Brazil-
dc.description.affiliationUniversidade Federal de Mato Grosso do Sul (UFMS), Quim Farmaceut Lab, Campo Grande, MS, Brazil-
dc.description.affiliationUnespUNESP, Lab Quim Organ, BR-11900000 Registro, SP, Brazil-
dc.identifier.doi10.1016/j.tetlet.2008.04.072-
dc.identifier.wosWOS:000256500500009-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofTetrahedron Letters-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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