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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/111421
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dc.contributor.authorCarvalho, Hudson W. P.-
dc.contributor.authorSantilli, Celso Valentim-
dc.contributor.authorBriois, Valerie-
dc.contributor.authorPulcinelli, Sandra Helena-
dc.date.accessioned2014-12-03T13:08:38Z-
dc.date.accessioned2016-10-25T20:08:28Z-
dc.date.available2014-12-03T13:08:38Z-
dc.date.available2016-10-25T20:08:28Z-
dc.date.issued2013-01-01-
dc.identifierhttp://dx.doi.org/10.1039/c3ra44388d-
dc.identifier.citationRsc Advances. Cambridge: Royal Soc Chemistry, v. 3, n. 45, p. 22830-22833, 2013.-
dc.identifier.issn2046-2069-
dc.identifier.urihttp://hdl.handle.net/11449/111421-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/111421-
dc.description.abstractThe radical trapping flame retardant mechanism of polymer-clay nanocomposites is frequently claimed to be responsible for improving the thermal stability of polymers. However it had never been demonstrated. Herein using in situ time-resolved X-ray Absorption Spectroscopy (XAS) we present experimental evidence that Fe3+ embedded in the clay can act as electron acceptors during polymer thermal decomposition. Therefore it contributes to improve the polymer thermal stability.en
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)-
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)-
dc.format.extent22830-22833-
dc.language.isoeng-
dc.publisherRoyal Soc Chemistry-
dc.sourceWeb of Science-
dc.titlePolymer-clay nanocomposites thermal stability: experimental evidence of the radical trapping effecten
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionSynchrotron SOLEIL-
dc.description.affiliationUNESP, Inst Chem, BR-14800900 Araraquara, Brazil-
dc.description.affiliationSynchrotron SOLEIL, F-91192 Lorme Des Merisiers, St Aubin, France-
dc.description.affiliationUnespUNESP, Inst Chem, BR-14800900 Araraquara, Brazil-
dc.description.sponsorshipIdCAPES: 564/07-
dc.description.sponsorshipIdFAPESP: 114364-
dc.identifier.doi10.1039/c3ra44388d-
dc.identifier.wosWOS:000326395800009-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofRsc Advances-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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