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DC Field | Value | Language |
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dc.contributor.author | Carvalho, Hudson W. P. | - |
dc.contributor.author | Santilli, Celso Valentim | - |
dc.contributor.author | Briois, Valerie | - |
dc.contributor.author | Pulcinelli, Sandra Helena | - |
dc.date.accessioned | 2014-12-03T13:08:38Z | - |
dc.date.accessioned | 2016-10-25T20:08:28Z | - |
dc.date.available | 2014-12-03T13:08:38Z | - |
dc.date.available | 2016-10-25T20:08:28Z | - |
dc.date.issued | 2013-01-01 | - |
dc.identifier | http://dx.doi.org/10.1039/c3ra44388d | - |
dc.identifier.citation | Rsc Advances. Cambridge: Royal Soc Chemistry, v. 3, n. 45, p. 22830-22833, 2013. | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | http://hdl.handle.net/11449/111421 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/111421 | - |
dc.description.abstract | The radical trapping flame retardant mechanism of polymer-clay nanocomposites is frequently claimed to be responsible for improving the thermal stability of polymers. However it had never been demonstrated. Herein using in situ time-resolved X-ray Absorption Spectroscopy (XAS) we present experimental evidence that Fe3+ embedded in the clay can act as electron acceptors during polymer thermal decomposition. Therefore it contributes to improve the polymer thermal stability. | en |
dc.description.sponsorship | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | - |
dc.description.sponsorship | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | - |
dc.description.sponsorship | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | - |
dc.format.extent | 22830-22833 | - |
dc.language.iso | eng | - |
dc.publisher | Royal Soc Chemistry | - |
dc.source | Web of Science | - |
dc.title | Polymer-clay nanocomposites thermal stability: experimental evidence of the radical trapping effect | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.contributor.institution | Synchrotron SOLEIL | - |
dc.description.affiliation | UNESP, Inst Chem, BR-14800900 Araraquara, Brazil | - |
dc.description.affiliation | Synchrotron SOLEIL, F-91192 Lorme Des Merisiers, St Aubin, France | - |
dc.description.affiliationUnesp | UNESP, Inst Chem, BR-14800900 Araraquara, Brazil | - |
dc.description.sponsorshipId | CAPES: 564/07 | - |
dc.description.sponsorshipId | FAPESP: 114364 | - |
dc.identifier.doi | 10.1039/c3ra44388d | - |
dc.identifier.wos | WOS:000326395800009 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Rsc Advances | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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