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dc.contributor.authorGraciela Aguayo, Maria-
dc.contributor.authorFerraz, Andre-
dc.contributor.authorElissetche, Juan Pedro-
dc.contributor.authorMasarin, Fernando-
dc.contributor.authorMendonca, Regis Teixeira-
dc.date.accessioned2015-03-18T15:56:06Z-
dc.date.accessioned2016-10-25T20:35:19Z-
dc.date.available2015-03-18T15:56:06Z-
dc.date.available2016-10-25T20:35:19Z-
dc.date.issued2014-08-01-
dc.identifierhttp://dx.doi.org/10.1515/hf-2013-0190-
dc.identifier.citationHolzforschung. Berlin: Walter De Gruyter Gmbh, v. 68, n. 6, p. 623-629, 2014.-
dc.identifier.issn0018-3830-
dc.identifier.urihttp://hdl.handle.net/11449/117421-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/117421-
dc.description.abstractEucalyptus globulus Labill. is a short-fibre resource for pulp and paper production. Ten different E. globulus genotypes with varied pulpwood quality and chemical composition were evaluated under kraft pulping conditions. Characterisation of the wood and pulp samples by thioacidolysis indicated that the content of syringyl units in beta-O-4 linkages (S-beta-O-4) was distinct for the studied genotypes. The highest S-beta-O-4 levels were detected in the samples with the lowest original lignin and highest glucan levels. This group of samples provided the pulps with the lowest final lignin content at higher yields. UV microspectrophotometric (UMSP) evaluation of the wood chips revealed that the samples with the lowest lignin levels have the lowest UV absorbances at 278 nm (A(278 nm)) in the secondary walls (S-2). During kraft pulping, lignin from the S-2 was dissolved, whereas lignins from the middle lamella and cell corner lignin was not removed not even for prolonged reaction periods, independently of the evaluated genotype. The A(278 nm) values of the S-2 were significantly lower in the pulps from the genotypes with less original lignin content.en
dc.description.sponsorshipFONDECYT-
dc.description.sponsorshipINNOVA-CHILE in Chile-
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
dc.description.sponsorshipMECESUP-
dc.format.extent623-629-
dc.language.isoeng-
dc.publisherWalter De Gruyter Gmbh-
dc.sourceWeb of Science-
dc.subjectaryl-ether linkages (beta-O-4 linkages)en
dc.subjectEucalyptus globulusen
dc.subjectkraft pulpingen
dc.subjectligninen
dc.subjectsyringylen
dc.subjecttopochemistryen
dc.subjectUV microspectrophotometric (UMSP)en
dc.titleLignin chemistry and topochemistry during kraft delignification of Eucalyptus globulus genotypes with contrasting pulpwood characteristicsen
dc.typeoutro-
dc.contributor.institutionUniv Concepcion-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.description.affiliationUniv Concepcion, Fac Ciencias Forest, Concepcion, Chile-
dc.description.affiliationUniv Concepcion, Ctr Biotecnol, Concepcion, Chile-
dc.description.affiliationUniv Sao Paulo, Escola Engn Quim Lorena, Dept Biotecnol, Sao Paulo, Brazil-
dc.description.affiliationUniv Concepcion, Genom Forestal SA, Concepcion, Chile-
dc.description.affiliationUniv Estadual Paulista, Fac Ciencias Farmaceut, Dept Bioproc & Biotecnol, Araraquara, SP, Brazil-
dc.description.affiliationUnespUniv Estadual Paulista, Fac Ciencias Farmaceut, Dept Bioproc & Biotecnol, Araraquara, SP, Brazil-
dc.description.sponsorshipIdFONDECYT1110828-
dc.description.sponsorshipIdINNOVA-CHILE in Chile05CTE04-01-
dc.description.sponsorshipIdFAPESP: 11/50535-2-
dc.description.sponsorshipIdMECESUPUCO 0702-
dc.identifier.doi10.1515/hf-2013-0190-
dc.identifier.wosWOS:000342090900002-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofHolzforschung-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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