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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/20071
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dc.contributor.authorMarconato, J. C.-
dc.contributor.authorBulhoes, L. O.-
dc.contributor.authorTemperini, M. L.-
dc.date.accessioned2014-05-20T13:56:06Z-
dc.date.accessioned2016-10-25T17:05:34Z-
dc.date.available2014-05-20T13:56:06Z-
dc.date.available2016-10-25T17:05:34Z-
dc.date.issued1998-01-01-
dc.identifierhttp://dx.doi.org/10.1016/S0013-4686(97)00204-1-
dc.identifier.citationElectrochimica Acta. Oxford: Pergamon-Elsevier B.V., v. 43, n. 7, p. 771-780, 1998.-
dc.identifier.issn0013-4686-
dc.identifier.urihttp://hdl.handle.net/11449/20071-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/20071-
dc.description.abstractThe effect of 2-mercaptobenzothiazole (MBT) on the corrosion of copper in ethanol-water mixture with 0.01 mol dm(-3) HClO4 was investigated by linear sweep voltammetry and surface enhanced Raman scattering spectroscopy. The linear sweep voltammetry for the copper electrode in the presence of MBT shows one anodic process associated with the oxidation of MBT, which leads to the formation of a film on the electrode. This film inhibits the anodic copper dissolution and cathodic hydrogen evolution reaction. SERS studies indicated that MBT oxidizes and forms polymeric complexes involving copper ions and the ionized form of thiol. (C) 1997 Elsevier B.V. Ltd.en
dc.format.extent771-780-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.sourceWeb of Science-
dc.subject2-mercaptobenzothiazolept
dc.subjectSERSpt
dc.subjectethanolpt
dc.subjectcopper corrosionpt
dc.titleA spectroelectrochemical study of the inhibition of the electrode process on copper by 2-mercaptobenzothiazole in ethanolic solutionsen
dc.typeoutro-
dc.contributor.institutionUniversidade Federal de São Carlos (UFSCar)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.description.affiliationUniv Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil-
dc.description.affiliationUNESP, Inst Biociencias, Dept Bioquim & Microbiol, BR-13506900 Rio Claro, SP, Brazil-
dc.description.affiliationUniv São Paulo, Inst Quim, BR-01452990 São Paulo, Brazil-
dc.description.affiliationUnespUNESP, Inst Biociencias, Dept Bioquim & Microbiol, BR-13506900 Rio Claro, SP, Brazil-
dc.identifier.doi10.1016/S0013-4686(97)00204-1-
dc.identifier.wosWOS:000071490500016-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofElectrochimica Acta-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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