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DC Field | Value | Language |
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dc.contributor.author | Bergamini, Marcio F. | - |
dc.contributor.author | Santos, Daniela P. | - |
dc.contributor.author | Zanoni, Maria Valnice Boldrin | - |
dc.date.accessioned | 2014-05-20T14:19:13Z | - |
dc.date.accessioned | 2016-10-25T17:40:57Z | - |
dc.date.available | 2014-05-20T14:19:13Z | - |
dc.date.available | 2016-10-25T17:40:57Z | - |
dc.date.issued | 2010-02-01 | - |
dc.identifier | http://dx.doi.org/10.1016/j.bioelechem.2009.07.010 | - |
dc.identifier.citation | Bioelectrochemistry. Lausanne: Elsevier B.V. Sa, v. 77, n. 2, p. 133-138, 2010. | - |
dc.identifier.issn | 1567-5394 | - |
dc.identifier.uri | http://hdl.handle.net/11449/25795 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/25795 | - |
dc.description.abstract | A sensitive voltammetric method for trace measurements of isoniazid (INZ) in synthetic human urine sample is described. The method is based on its electroreduction at -0.98 V vs. Ag/AgCl on screen-printed carbon electrode (SPCE) modified with poly-L-histidine (PH). A film of good adherence on SPCE and electrocatalytic properties was obtained coating the electrode by histidine monomer electropolymerization process (SPCE/EPH). The electrochemical behavior of the modified SPCE was investigated by cyclic, linear sweep (LSV), differential pulse (DPV). square-wave voltammetry (SWV), and electrochemical impedance spectroscopy (EIS). Limits of detection of 5.0 x 10(-7) mol L(-1), 1.7 x 10(-7) mol L(-1) and 2.5 x 10(-7) mol L(-1) were estimated from LSV, DPV and SWV determinations, respectively. The method was successfully applied to the determination of INZ in human urine samples. (c) 2009 Elsevier B.V. All rights reserved. | en |
dc.description.sponsorship | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | - |
dc.description.sponsorship | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) | - |
dc.description.sponsorship | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | - |
dc.format.extent | 133-138 | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. Sa | - |
dc.source | Web of Science | - |
dc.subject | Screen-printed electrode | en |
dc.subject | Modified electrode | en |
dc.subject | Poly-L-histidine | en |
dc.subject | Isoniazid | en |
dc.subject | Determination | en |
dc.title | Determination of isoniazid in human urine using screen-printed carbon electrode modified with poly-L-histidine | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.contributor.institution | Universidade Federal do Paraná (UFPR) | - |
dc.description.affiliation | UNESP, Inst Chem, BR-14801970 Araraquara, SP, Brazil | - |
dc.description.affiliation | UFPR, Ctr Politecn, Dept Quim, Setor Ciencias Exatas, BR-81531990 Curitiba, Parana, Brazil | - |
dc.description.affiliationUnesp | UNESP, Inst Chem, BR-14801970 Araraquara, SP, Brazil | - |
dc.description.sponsorshipId | FAPESP: 03/06598-3 | - |
dc.description.sponsorshipId | FAPESP: 04/00111-8 | - |
dc.identifier.doi | 10.1016/j.bioelechem.2009.07.010 | - |
dc.identifier.wos | WOS:000275232600010 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Bioelectrochemistry | - |
dc.identifier.orcid | 0000-0002-2296-1393 | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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