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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/26341
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dc.contributor.authorFelippe, Lidiane G.-
dc.contributor.authorBatista, Joao M.-
dc.contributor.authorBaldoqui, Debora Cristina-
dc.contributor.authorNascimento, Isabele Rodrigues-
dc.contributor.authorKato, Massuo J.-
dc.contributor.authorHe, Yanan-
dc.contributor.authorNafie, Laurence A.-
dc.contributor.authorFurlan, Maysa-
dc.date.accessioned2014-05-20T14:21:12Z-
dc.date.accessioned2016-10-25T17:41:53Z-
dc.date.available2014-05-20T14:21:12Z-
dc.date.available2016-10-25T17:41:53Z-
dc.date.issued2012-01-01-
dc.identifierhttp://dx.doi.org/10.1039/c2ob25109d-
dc.identifier.citationOrganic & Biomolecular Chemistry. Cambridge: Royal Soc Chemistry, v. 10, n. 21, p. 4208-4214, 2012.-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/11449/26341-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/26341-
dc.description.abstractThe absolute configuration and solution-state conformers of three peperomin-type secolignans isolated from Peperomia blanda (Piperaceae) are unambiguously determined by using vibrational circular dichroism (VCD) spectroscopy associated with density functional theory (DFT) calculations. Advantages of VCD over the electronic form of CD for the analysis of diastereomers are also discussed. This work extends our growing knowledge about secondary metabolites within the Piperaceae family species while providing a definitive and straightforward method to assess the absolute stereochemistry of secolignans.en
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)-
dc.description.sponsorshipCenter for Scientific Computing (NCC/GridUNESP) of the São Paulo State University (UNESP)-
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)-
dc.format.extent4208-4214-
dc.language.isoeng-
dc.publisherRoyal Soc Chemistry-
dc.sourceWeb of Science-
dc.titleVCD to determine absolute configuration of natural product molecules: secolignans from Peperomia blandaen
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade Estadual de Maringá (UEM)-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.contributor.institutionBioTools Inc-
dc.contributor.institutionSyracuse Univ-
dc.description.affiliationSão Paulo State Univ UNESP, Dept Organ Chem, Inst Chem, BR-14800900 Araraquara, SP, Brazil-
dc.description.affiliationUniversidade Estadual de Maringá (UEM), Dept Chem, BR-87020900 Maringa, Parana, Brazil-
dc.description.affiliationUniv São Paulo, Dept Fundamental Chem, Inst Chem, BR-05508000 São Paulo, SP, Brazil-
dc.description.affiliationBioTools Inc, Jupiter, FL 33458 USA-
dc.description.affiliationSyracuse Univ, Dept Chem, Syracuse, NY 13244 USA-
dc.description.affiliationUnespSão Paulo State Univ UNESP, Dept Organ Chem, Inst Chem, BR-14800900 Araraquara, SP, Brazil-
dc.description.sponsorshipIdFAPESP: 09/51850-9-
dc.description.sponsorshipIdFAPESP: 08/58658-3-
dc.identifier.doi10.1039/c2ob25109d-
dc.identifier.wosWOS:000303768700008-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofOrganic & Biomolecular Chemistry-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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