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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/27564
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dc.contributor.authorZamian, José Roberto-
dc.contributor.authorMauro, Antonio Eduardo-
dc.contributor.authorNogueira, Vânia Martins-
dc.date.accessioned2014-05-20T15:10:17Z-
dc.date.accessioned2016-10-25T17:44:41Z-
dc.date.available2014-05-20T15:10:17Z-
dc.date.available2016-10-25T17:44:41Z-
dc.date.issued1999-12-01-
dc.identifierhttp://dx.doi.org/10.1590/S0100-40421999000600003-
dc.identifier.citationQuímica Nova. Sociedade Brasileira de Química, v. 22, n. 6, p. 787-789, 1999.-
dc.identifier.issn0100-4042-
dc.identifier.urihttp://hdl.handle.net/11449/27564-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/27564-
dc.description.abstractThe series of compounds cis-[Fe(CO)4(HgX)2], X=Cl,Br,I shows an octahedral geometry around the iron atom with the two HgX groups cis to each other. In this paper the assignment for the carbonyl stretching modes and the calculation of their force constants were performed on the basis of the Cotton-Krainhanzel model. Taking into account all the data from the IR, 199Hg NMR and UV-vis spectra it is possible to verify the influence of X on the electronic densities at the metallic centers.en
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)-
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)-
dc.format.extent787-789-
dc.language.isopor-
dc.publisherSociedade Brasileira de Química-
dc.sourceSciELO-
dc.subjectiron carbonylsen
dc.subjectmercuryen
dc.subjectspectroscopic studiesen
dc.titleInvestigação espectroscópica dos carbonilos heterobimetálicos cis-[Fe(CO)4(HgX)2], X = Cl, Br,Ipt
dc.title.alternativeSpectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)4(HgX)2], X=Cl, Br, Ien
dc.typeoutro-
dc.contributor.institutionUniversidade Federal do Pará (UFPA)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.description.affiliationUniversidade Federal do Pará (UFPA) Centro de Ciências Exatas e Naturais Departamento de Química-
dc.description.affiliationUniversidade Estadual Paulista Instituto de Química-
dc.description.affiliationUnespUniversidade Estadual Paulista Instituto de Química-
dc.identifier.doi10.1590/S0100-40421999000600003-
dc.identifier.scieloS0100-40421999000600003-
dc.rights.accessRightsAcesso aberto-
dc.identifier.fileS0100-40421999000600003.pdf-
dc.relation.ispartofQuímica Nova-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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