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http://acervodigital.unesp.br/handle/11449/32498
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DC Field | Value | Language |
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dc.contributor.author | Wohnrath, K. | - |
dc.contributor.author | de Araujo, M. P. | - |
dc.contributor.author | Dinelli, L. R. | - |
dc.contributor.author | Batista, A. A. | - |
dc.contributor.author | Moreira, I. D. | - |
dc.contributor.author | Castellano, E. E. | - |
dc.contributor.author | Ellena, J. | - |
dc.date.accessioned | 2014-05-20T15:21:20Z | - |
dc.date.accessioned | 2016-10-25T17:54:44Z | - |
dc.date.available | 2014-05-20T15:21:20Z | - |
dc.date.available | 2016-10-25T17:54:44Z | - |
dc.date.issued | 2000-01-01 | - |
dc.identifier | http://dx.doi.org/10.1039/b001422m | - |
dc.identifier.citation | Journal of the Chemical Society-dalton Transactions. Cambridge: Royal Soc Chemistry, n. 19, p. 3383-3386, 2000. | - |
dc.identifier.issn | 1470-479X | - |
dc.identifier.uri | http://hdl.handle.net/11449/32498 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/32498 | - |
dc.description.abstract | Electrolysis has been examined as a method of synthesis for [(L)(dppb)Ru(mu-Cl)(3)RuCl(dppb)] complexes, where dppb = 1,4-bis(diphenylphosphino)butane and L = pyridine (py), 4-methylpyridine (4-pic) or dimethyl sulfoxide (DMSO), by using [RuCl3(dppb)(L)] as precursors. The products of the electrolysis were characterized by P-31-{H-1} NMR, cyclic voltammetry and near infrared spectroscopy. The presence of the [Ru2Cl5(dppb)(2)] complex in the electrochemical cell suggests a mechanism by which the starting original species from the bulk solution reacts with the reduced form [RuCl2(dppb)(L)] generated at the surface of the electrode. The crystal structure of the precursor mer-[RuCl3(dppb)(4-pic)] was determined by X-ray diffraction. | en |
dc.format.extent | 3383-3386 | - |
dc.language.iso | eng | - |
dc.publisher | Royal Soc Chemistry | - |
dc.source | Web of Science | - |
dc.title | Electrosynthesis of binuclear ruthenium complexes from [RuCl3(dppb)(L)] precursors [L = pyridine, 4-methylpyridine or dimethyl sulfoxide; dppb=1,4-bis(diphenylphosphino)butane] | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Federal de São Carlos (UFSCar) | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.contributor.institution | Universidade Federal do Ceará (UFC) | - |
dc.contributor.institution | Universidade de São Paulo (USP) | - |
dc.description.affiliation | Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil | - |
dc.description.affiliation | UNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil | - |
dc.description.affiliation | Univ Fed Ceara, Dept Quim Organ & Inorgan, Fortaleza, Ceara, Brazil | - |
dc.description.affiliation | Univ São Paulo, Inst Fis, Dept Fis & Informat, BR-13560970 Sao Carlos, SP, Brazil | - |
dc.description.affiliationUnesp | UNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil | - |
dc.identifier.doi | 10.1039/b001422m | - |
dc.identifier.wos | WOS:000089553100023 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Journal of the Chemical Society: Dalton Transactions | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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