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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/32883
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dc.contributor.authorJorge, SMA-
dc.contributor.authorde Sene, J. J.-
dc.contributor.authorStradiotto, Nelson Ramos-
dc.date.accessioned2014-05-20T15:21:46Z-
dc.date.accessioned2016-10-25T17:55:18Z-
dc.date.available2014-05-20T15:21:46Z-
dc.date.available2016-10-25T17:55:18Z-
dc.date.issued2006-04-01-
dc.identifierhttp://dx.doi.org/10.1134/S1023193506040070-
dc.identifier.citationRussian Journal of Electrochemistry. New York: Maik Nauka/interperiodica/springer, v. 42, n. 4, p. 326-330, 2006.-
dc.identifier.issn1023-1935-
dc.identifier.urihttp://hdl.handle.net/11449/32883-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/32883-
dc.description.abstractThe electrochemical reduction of serine, glycine, and leucine protected by the 4-nitrobenzenesulfonyl, group in N,N-dimethylformamide at mercury cathode occurs at two steps. The first one at -0.8 V vs. SCE, after a one-electron transfer, leads the anion radical formation that dimerizes and adsorbs at electrode. In the second step at -1.4 V, an instable dianion forms which then cleaves. The mechanism is discussed.en
dc.format.extent326-330-
dc.language.isoeng-
dc.publisherSpringer-
dc.sourceWeb of Science-
dc.subjectnitrobenzenesulfonyl grouppt
dc.subjectserinept
dc.subjectglycinept
dc.subjectleucinept
dc.subjectcathodic cleavagept
dc.titleElectrochemical behavior of the N-nosyl-protected amino acids in N,N-dimethylformamideen
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionFundação Educ Barretos-
dc.description.affiliationUniv Estadual Paulista Julio Mesquita Filho, Inst Biociencias, BR-18618000 Botucatu, SP, Brazil-
dc.description.affiliationFundação Educ Barretos, BR-14783226 Barretos, SP, Brazil-
dc.description.affiliationUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil-
dc.description.affiliationUnespUniv Estadual Paulista Julio Mesquita Filho, Inst Biociencias, BR-18618000 Botucatu, SP, Brazil-
dc.description.affiliationUnespUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil-
dc.identifier.doi10.1134/S1023193506040070-
dc.identifier.wosWOS:000237052600007-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofRussian Journal of Electrochemistry-
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