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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/33241
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dc.contributor.authorMelnikov, P.-
dc.contributor.authorCorbi, P. P.-
dc.contributor.authorAguila, C. D.-
dc.contributor.authorZacharias, M. A.-
dc.contributor.authorCavicchioli, M.-
dc.contributor.authorMassabni, Antonio Carlos-
dc.date.accessioned2014-05-20T15:22:14Z-
dc.date.accessioned2016-10-25T17:55:51Z-
dc.date.available2014-05-20T15:22:14Z-
dc.date.available2016-10-25T17:55:51Z-
dc.date.issued2000-07-14-
dc.identifierhttp://dx.doi.org/10.1016/S0925-8388(00)00884-7-
dc.identifier.citationJournal of Alloys and Compounds. Lausanne: Elsevier B.V. Sa, v. 307, p. 179-183, 2000.-
dc.identifier.issn0925-8388-
dc.identifier.urihttp://hdl.handle.net/11449/33241-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/33241-
dc.description.abstractDjenkolate complex of iron, [Fe(C(7)H(12)N(2)O(4)S(2))]. H(2)O, has been synthesized by the reaction of potassium djenkolate with Fe(SO(4)). 7H(2)O under nitrogen atmosphere. X-Ray diffraction pattern has been indexed in orthorhombic system with lattice parameters: a=11.24 Angstrom, b=7.50 Angstrom and c=6.96 Angstrom. According to IR spectroscopy, coordination is performed through COO(-) and NH(2) groups. An octahedral geometry for Fe ion is suggested by UV-Vis and Mossbauer spectroscopies. Thermal decomposition leads to the formation of Fe(2)O(3) (hematite). The compound shows poor solubility in water and in common organic solvents. (C) 2000 Elsevier B.V. S.A. All rights reserved.en
dc.format.extent179-183-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.sourceWeb of Science-
dc.subjectx-ray diffractionpt
dc.titleIron(II) djenkolate: synthesis and propertiesen
dc.typeoutro-
dc.contributor.institutionUniversidade Federal de Mato Grosso do Sul (UFMS)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniv La Habana-
dc.description.affiliationUniv Fed Mato Grosso do Sul, CCET, BR-79070900 Campo Grande, MS, Brazil-
dc.description.affiliationUNESP, Dept Quim Geral & Inorgan, Inst Quim, BR-14800900 Araraquara, SP, Brazil-
dc.description.affiliationUniv La Habana, Ctr Biomat, Havana 10400, Cuba-
dc.description.affiliationUnespUNESP, Dept Quim Geral & Inorgan, Inst Quim, BR-14800900 Araraquara, SP, Brazil-
dc.identifier.doi10.1016/S0925-8388(00)00884-7-
dc.identifier.wosWOS:000088590900029-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofJournal of Alloys and Compounds-
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