Please use this identifier to cite or link to this item:
http://acervodigital.unesp.br/handle/11449/35480
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lang, E. S. | - |
dc.contributor.author | Ledesma, G. N. | - |
dc.contributor.author | Abram, U. | - |
dc.contributor.author | Vega-Teijido, M. | - |
dc.contributor.author | Caracelli, I | - |
dc.contributor.author | Zukerman-Schpector, J. | - |
dc.date.accessioned | 2014-05-20T15:25:00Z | - |
dc.date.accessioned | 2016-10-25T17:59:19Z | - |
dc.date.available | 2014-05-20T15:25:00Z | - |
dc.date.available | 2016-10-25T17:59:19Z | - |
dc.date.issued | 2006-01-01 | - |
dc.identifier | http://dx.doi.org/10.1524/zkri.2006.221.2.166 | - |
dc.identifier.citation | Zeitschrift Fur Kristallographie. Munich: Oldenbourg Verlag, v. 221, n. 2, p. 166-172, 2006. | - |
dc.identifier.issn | 0044-2968 | - |
dc.identifier.uri | http://hdl.handle.net/11449/35480 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/35480 | - |
dc.description.abstract | (1) C11H17IN2STe, Mr = 463.83, P2(1)/n, a 7.6582(8), b = 13.8008(9), c = 15.026(3) angstrom, beta = 96.233(12)degrees, Z = 4, R-1 = 0.0318. (2) C15H19IN2STe, Mr = 513.88, P2(1)/n, a = 8.434(5), b = 11.697(5), c = 18.472(5) angstrom, beta = 98.556(5)degrees, Z = 4, R-1 = 0.0236. The synthesis of the aryltellurenyl N,N',-tetramethylthiourea (tmtu) iodide has been performed by ligand exchange with potassium iodide and the corresponding aryltellurenyl(tmtu) bromide. In both structures the tellurium atom is primarily three-coordinated, being bonded to a carbon atom of the organic ring and, in directions nearly perpendicular to the Te-C bond, to one tmtu sulfur atom and one iodine. In addition there are Te...secondary bonds, joining the molecules in centrosymmetric dimers, which in turn are joined through C-H...1 and C-H... S interactions, in (1) and (2), respectively. | en |
dc.format.extent | 166-172 | - |
dc.language.iso | eng | - |
dc.publisher | Oldenbourg Verlag | - |
dc.source | Web of Science | - |
dc.subject | tellurium(II) | pt |
dc.subject | tetramethylthiourea | pt |
dc.subject | supramolecular | pt |
dc.subject | X-ray diffraction | pt |
dc.subject | single crystal structure analysis | pt |
dc.title | Synthesis, crystal structure and theoretical studies of aryltellurenyl tetramethylthiourea(tmtu) iodine complexes: Ph-Te(tmtu)I (1) and beta-naphtyl-Te(tmtu)I (2) | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Federal de Sergipe (UFS) | - |
dc.contributor.institution | Freien Univ | - |
dc.contributor.institution | Universidade Federal de São Carlos (UFSCar) | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.description.affiliation | Universidade Federal de Santa Maria (UFSM), Dept Quim, Lab Mat Inorgan, BR-97105900 Santa Maria, RS, Brazil | - |
dc.description.affiliation | Freien Univ, Inst Chem, Berlin, Germany | - |
dc.description.affiliation | Univ Fed Sao Carlos, Dept Quim, Lab Cristalog Estereodinam & Modelagem Mol, BR-13565905 Sao Carlos, SP, Brazil | - |
dc.description.affiliation | UNESP, Fac Ciências, Bauru, SP, Brazil | - |
dc.description.affiliationUnesp | UNESP, Fac Ciências, Bauru, SP, Brazil | - |
dc.identifier.doi | 10.1524/zkri.2006.221.2.166 | - |
dc.identifier.wos | WOS:000235609900008 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Zeitschrift Fur Kristallographie | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.