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DC Field | Value | Language |
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dc.contributor.author | Batista, A. A. | - |
dc.contributor.author | Pereira, C. | - |
dc.contributor.author | Queiroz, S. L. | - |
dc.contributor.author | deOliveira, LAA | - |
dc.contributor.author | Santos, RHD | - |
dc.contributor.author | Gambardella, MTD | - |
dc.date.accessioned | 2014-05-20T15:25:04Z | - |
dc.date.accessioned | 2016-10-25T17:59:26Z | - |
dc.date.available | 2014-05-20T15:25:04Z | - |
dc.date.available | 2016-10-25T17:59:26Z | - |
dc.date.issued | 1997-01-01 | - |
dc.identifier | http://dx.doi.org/10.1016/S0277-5387(96)00350-6 | - |
dc.identifier.citation | Polyhedron. Oxford: Pergamon-Elsevier B.V., v. 16, n. 6, p. 927-931, 1997. | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/11449/35550 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/35550 | - |
dc.description.abstract | Ruthenium(II) complexes with general formula [RuCl3(NO)(P-P)] were obtained in the solid state, where P-P = PPh(2)(CH2)(n)PPh(2) (n = 1-3) and PPh(2)-CH = CH-PPh(2). The P-31 NMR spectra of these compounds measured in CH2Cl2 showed only singlets, consistent with a fac configuration containing two equivalent phosphorus atoms, However the X-ray diffraction data show that the [RuCl3(NO){PPh(2)(CH2)(3)PPh(2)}] complex crystallizes in a met configuration, where one of the phosphorus atoms is trans to the NO group, in a slightly distorted octahedral geometry. Copyright (C) 1996 Elsevier B.V. Ltd | en |
dc.format.extent | 927-931 | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.source | Web of Science | - |
dc.subject | ruthenium | pt |
dc.subject | nitrosyl | pt |
dc.subject | complexes | pt |
dc.subject | biphosphines | pt |
dc.subject | X-ray structure | pt |
dc.subject | isomerism | pt |
dc.title | Nitrosyl ruthenium complexes with general formula [RuCl3,(NO)(P-P)] (P-P={PPh(2)(CH2)(n)PPh(2)},n=1-3 and {PPh(2)-CH=CH-PPh(2)}). X-ray structure of [RuCl3(NO){PPh(2)(CH2)(3)PPh(2)}] | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.contributor.institution | Universidade de São Paulo (USP) | - |
dc.description.affiliation | UNESP,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL | - |
dc.description.affiliation | UNIV SAO PAULO,INST QUIM,BR-13560970 SAO CARLOS,SP,BRAZIL | - |
dc.description.affiliationUnesp | UNESP,INST QUIM,BR-14800900 ARARAQUARA,SP,BRAZIL | - |
dc.identifier.doi | 10.1016/S0277-5387(96)00350-6 | - |
dc.identifier.wos | WOS:A1997VY19400008 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Polyhedron | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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