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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/36889
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dc.contributor.authorNetto, AVG-
dc.contributor.authorMauro, A. E.-
dc.contributor.authorFrem, RCG-
dc.contributor.authorSantana, A. M.-
dc.contributor.authorSantos, RHA-
dc.contributor.authorZoia, JR-
dc.date.accessioned2014-05-20T15:26:48Z-
dc.date.accessioned2016-10-25T18:01:27Z-
dc.date.available2014-05-20T15:26:48Z-
dc.date.available2016-10-25T18:01:27Z-
dc.date.issued2001-01-01-
dc.identifierhttp://dx.doi.org/10.1080/00958970108027149-
dc.identifier.citationJournal of Coordination Chemistry. Philadelphia: Gordon Breach Publishing, Taylor & Francis Group, v. 54, n. 2, p. 129-141, 2001.-
dc.identifier.issn0095-8972-
dc.identifier.urihttp://hdl.handle.net/11449/36889-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/36889-
dc.description.abstractMononuclear pyrazolyl Pd(II) complexes of the type [PdX2(phmPz)(2)] (X = Cl-, N-3(-)) have been prepared. The 1-phenyl-3-methylpyrazole displaces acetonitrile from [PdCl2(CH3CN)(2)] to form [PdCl2(PhMPz)(2)] (phmPz = 1-phenyl-3-methylpyrazole) (1). [Pd(N-3)(2)(PhmPz)(2)] (2) could be obtained by metathesis from [PdCl2(CH3CN)(2)] or by substitution of the chloride in (1) by the azide ion. Both complexes were characterized by elemental analysis, infrared spectroscopy, H-1 and C-13 NMR and by single crystal X-ray diffraction. The coordination geometry around Pd(II) in these complexes is nearly square-planar, with the ligands in a trans configuration.en
dc.format.extent129-141-
dc.language.isoeng-
dc.publisherGordon Breach Publishing, Taylor & Francis Group-
dc.sourceWeb of Science-
dc.subjectpyrazolept
dc.subjectpalladium(II)pt
dc.subjectazidept
dc.subjectinfrared spectroscopypt
dc.subjectNMR spectroscopypt
dc.subjectX-ray diffractionpt
dc.titleSynthesis and structural characterization of dichlorobis (1-phenyl-3-methylpyrazole) palladium(II) and diazidobis (1-phenyl-3-methylpyrazole) palladiium(II)en
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.description.affiliationUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil-
dc.description.affiliationUSP, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil-
dc.description.affiliationUnespUNESP, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil-
dc.identifier.doi10.1080/00958970108027149-
dc.identifier.wosWOS:000170693300004-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofJournal of Coordination Chemistry-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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