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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/39061
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dc.contributor.authorJorge, SMA-
dc.contributor.authorStradiotto, N. R.-
dc.date.accessioned2014-05-20T15:29:28Z-
dc.date.accessioned2016-10-25T18:04:45Z-
dc.date.available2014-05-20T15:29:28Z-
dc.date.available2016-10-25T18:04:45Z-
dc.date.issued1996-10-30-
dc.identifierhttp://dx.doi.org/10.1016/S0022-0728(96)04610-4-
dc.identifier.citationJournal of Electroanalytical Chemistry. Lausanne 1: Elsevier B.V. Sa Lausanne, v. 415, n. 1-2, p. 27-32, 1996.-
dc.identifier.issn0022-0728-
dc.identifier.urihttp://hdl.handle.net/11449/39061-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/39061-
dc.description.abstractThe applicability of the nitrobenzoyl group [NO2C6H4CO-] to protecting the functional hydroxyl group was investigated through study of the electrochemical behaviour of the butyl 4-, 3- and 2-nitrobenzoate compounds. These isomers are reduced in two cathodic steps. The first, at potentials of ca. -0.9 V vs. SCE, is attributed to the formation of rather stable anion radicals, involving one-electron transfer. The second, at potentials of ca. -1.7 V vs. SCE, occurs with a two-electron transfer in an ECE process, in which the dianion produced undergoes scission of the C-O bond giving n-butanoate ions with high yields (similar to 80%)en
dc.format.extent27-32-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.sourceWeb of Science-
dc.subjectelectrochemical cleavagept
dc.subjectnitrobenzoylpt
dc.subjectbutyl nitrobenzoatespt
dc.titleThe electrochemical cleavage of the nitrobenzoyl group from butyl nitrobenzoates in N,N-dimethylformamideen
dc.typeoutro-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.description.affiliationUSP,FAC FILOSOFIA CIENCIAS & LETRAS RIBEIRAO PRET,DEPT QUIM,BR-14040901 RIBEIRAO PRET,SP,BRAZIL-
dc.description.affiliationUNIV ESTADUAL PAULISTA JULIO MESQUITA FILHO,INST BIOCIENCIAS,DEPT QUIM,BR-18618000 BOTUCATU,SP,BRAZIL-
dc.description.affiliationUnespUNIV ESTADUAL PAULISTA JULIO MESQUITA FILHO,INST BIOCIENCIAS,DEPT QUIM,BR-18618000 BOTUCATU,SP,BRAZIL-
dc.identifier.doi10.1016/S0022-0728(96)04610-4-
dc.identifier.wosWOS:A1996VR84100004-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofJournal of Electroanalytical Chemistry-
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