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DC Field | Value | Language |
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dc.contributor.author | Jorge, SMA | - |
dc.contributor.author | Stradiotto, N. R. | - |
dc.date.accessioned | 2014-05-20T15:29:28Z | - |
dc.date.accessioned | 2016-10-25T18:04:45Z | - |
dc.date.available | 2014-05-20T15:29:28Z | - |
dc.date.available | 2016-10-25T18:04:45Z | - |
dc.date.issued | 1996-10-30 | - |
dc.identifier | http://dx.doi.org/10.1016/S0022-0728(96)04610-4 | - |
dc.identifier.citation | Journal of Electroanalytical Chemistry. Lausanne 1: Elsevier B.V. Sa Lausanne, v. 415, n. 1-2, p. 27-32, 1996. | - |
dc.identifier.issn | 0022-0728 | - |
dc.identifier.uri | http://hdl.handle.net/11449/39061 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/39061 | - |
dc.description.abstract | The applicability of the nitrobenzoyl group [NO2C6H4CO-] to protecting the functional hydroxyl group was investigated through study of the electrochemical behaviour of the butyl 4-, 3- and 2-nitrobenzoate compounds. These isomers are reduced in two cathodic steps. The first, at potentials of ca. -0.9 V vs. SCE, is attributed to the formation of rather stable anion radicals, involving one-electron transfer. The second, at potentials of ca. -1.7 V vs. SCE, occurs with a two-electron transfer in an ECE process, in which the dianion produced undergoes scission of the C-O bond giving n-butanoate ions with high yields (similar to 80%) | en |
dc.format.extent | 27-32 | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.source | Web of Science | - |
dc.subject | electrochemical cleavage | pt |
dc.subject | nitrobenzoyl | pt |
dc.subject | butyl nitrobenzoates | pt |
dc.title | The electrochemical cleavage of the nitrobenzoyl group from butyl nitrobenzoates in N,N-dimethylformamide | en |
dc.type | outro | - |
dc.contributor.institution | Universidade de São Paulo (USP) | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.description.affiliation | USP,FAC FILOSOFIA CIENCIAS & LETRAS RIBEIRAO PRET,DEPT QUIM,BR-14040901 RIBEIRAO PRET,SP,BRAZIL | - |
dc.description.affiliation | UNIV ESTADUAL PAULISTA JULIO MESQUITA FILHO,INST BIOCIENCIAS,DEPT QUIM,BR-18618000 BOTUCATU,SP,BRAZIL | - |
dc.description.affiliationUnesp | UNIV ESTADUAL PAULISTA JULIO MESQUITA FILHO,INST BIOCIENCIAS,DEPT QUIM,BR-18618000 BOTUCATU,SP,BRAZIL | - |
dc.identifier.doi | 10.1016/S0022-0728(96)04610-4 | - |
dc.identifier.wos | WOS:A1996VR84100004 | - |
dc.rights.accessRights | Acesso restrito | - |
dc.relation.ispartof | Journal of Electroanalytical Chemistry | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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