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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/64297
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dc.contributor.authorMauro, Antonio Eduardo-
dc.contributor.authorPulcinelli, Sandra Helena-
dc.contributor.authorSantos, R. H A-
dc.contributor.authorGambardella, M. T P-
dc.date.accessioned2014-05-27T11:17:29Z-
dc.date.accessioned2016-10-25T18:13:01Z-
dc.date.available2014-05-27T11:17:29Z-
dc.date.available2016-10-25T18:13:01Z-
dc.date.issued1992-12-01-
dc.identifierhttp://dx.doi.org/10.1016/S0277-5387(00)86013-1-
dc.identifier.citationPolyhedron, v. 11, n. 7, p. 799-803, 1992.-
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/11449/64297-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/64297-
dc.description.abstractThe bis(1,10-phenanthrolinethiocyanatemercury)tetracarbonyliron was prepared from bis(thiocyanatemercury)tetracarbonyliron and 1,10-phenanthroline and crystallized from hot acetone solution as [Fe(CO)4(HgSCN)2(phen)2]·C3H6O, which was subjected to a full IR and X-ray crystallographic characterization. The iron atom is octahedrally coordinated by four carbonyl groups and two mercury atoms in cis positions. The coordination geometry of the mercury atoms is a distorted square-based pyramid since each one is coordinated to one iron, one sulphur, one mercury and two nitrogen atoms. The FeHg distances are 2.549(3) and 2.564(3) Å, and the HgFeHg angle is 78.01(9)°. © 1992.en
dc.format.extent799-803-
dc.language.isoeng-
dc.sourceScopus-
dc.titleSynthesis and structural studies of bis(1,10-phenanthrolinethiocyanatemercury) tetracarbonylironen
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade de São Paulo (USP)-
dc.description.affiliationInstituto de Química de Araraquara UNESP, C.P. 355, 14800 Araraquara-
dc.description.affiliationInstituto de Física e Química de São Carlos USP, C.P. 369, 13560 São Carlos-
dc.description.affiliationUnespInstituto de Química de Araraquara UNESP, C.P. 355, 14800 Araraquara-
dc.identifier.doi10.1016/S0277-5387(00)86013-1-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofPolyhedron-
dc.identifier.scopus2-s2.0-0012030795-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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