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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Mazzetto, Selma Elaine | - |
| dc.contributor.author | De Almeida Plicas, Lidia Maria | - |
| dc.contributor.author | Tfouni, Elia | - |
| dc.contributor.author | Franco, Douglas Wagner | - |
| dc.date.accessioned | 2014-05-27T11:17:29Z | - |
| dc.date.accessioned | 2016-10-25T18:13:01Z | - |
| dc.date.available | 2014-05-27T11:17:29Z | - |
| dc.date.available | 2016-10-25T18:13:01Z | - |
| dc.date.issued | 1992-12-01 | - |
| dc.identifier | http://dx.doi.org/10.1021/ic00029a033 | - |
| dc.identifier.citation | Inorganic Chemistry, v. 31, n. 3, p. 516-519, 1992. | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/11449/64299 | - |
| dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/64299 | - |
| dc.description.abstract | trans-[Ru(NH3)4P(OEt)3H2O] 2+, trans-[Ru(NH3)4(P(OEt)3)]2+, and trans-[Ru(NH3)4P(OEt)3CO]2+ were photolyzed with light of 313 nm on the lowest energy ligand field excited state. Photoaquation of the thermally substitution inert ammonia is observed for all three complexes with φ ≅ 0.30 mol/einstein. trans-[Ru(NH3)4(P(OEt)3)2] 2+ undergoes P(OEt)3 photoaquation with φ ≅ 0.12 mol/einstein, while trans-[Ru(NH3)4P(OEt)3CO]2+ displays CO photoaquation with φ = 0.07 mol/einstein. The results suggest that the electronic configuration of the lowest energy excited state of these complexes have contributions from E and A2 states. Furthermore, in trans-[Ru(NH3)4P(OEt)3CO]2+ the photoaquation of CO is explained by depopulation of a bonding dπ orbital and population of a σ* orbital. © 1992 American Chemical Society. | en |
| dc.format.extent | 516-519 | - |
| dc.language.iso | eng | - |
| dc.source | Scopus | - |
| dc.title | Phochemical behavior of trans-[Ru(NH3)4P(OEt)3L]2+ complex ions (L = P(OEt)3, CO, H2O) | en |
| dc.type | outro | - |
| dc.contributor.institution | Universidade de São Paulo (USP) | - |
| dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
| dc.description.affiliation | Institute de Física e Química de São Carlos-USP, C.P. 369, 13560 São Carlos-SP | - |
| dc.description.affiliation | Instituto de Biociências Letras e Ciências Exatas-UNESP, Sao Jose do Rio Preto-SP | - |
| dc.description.affiliation | Faculdade de Filosofia Ciências e Letras de Ribeirão Preto-USP, 14049 Ribeirão Preto-SP | - |
| dc.description.affiliationUnesp | Instituto de Biociências Letras e Ciências Exatas-UNESP, Sao Jose do Rio Preto-SP | - |
| dc.identifier.doi | 10.1021/ic00029a033 | - |
| dc.rights.accessRights | Acesso restrito | - |
| dc.relation.ispartof | Inorganic Chemistry | - |
| dc.identifier.scopus | 2-s2.0-33751391332 | - |
| Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp | |
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