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DC Field | Value | Language |
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dc.contributor.author | Boldrin Zanoni, M. V. | - |
dc.contributor.author | Rosa, I. L V | - |
dc.contributor.author | Pesquero, C. R. | - |
dc.contributor.author | Stradiotto, Nelson Ramos | - |
dc.date.accessioned | 2014-05-27T11:18:18Z | - |
dc.date.accessioned | 2016-10-25T18:14:47Z | - |
dc.date.available | 2014-05-27T11:18:18Z | - |
dc.date.available | 2016-10-25T18:14:47Z | - |
dc.date.issued | 1997-12-01 | - |
dc.identifier | http://dx.doi.org/10.1590/S0103-50531997000300007 | - |
dc.identifier.citation | Journal of the Brazilian Chemical Society, v. 8, n. 3, p. 223-227, 1997. | - |
dc.identifier.issn | 0103-5053 | - |
dc.identifier.uri | http://hdl.handle.net/11449/65293 | - |
dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/65293 | - |
dc.description.abstract | The electrochemical behavior of aniline protected by a nitrobenzene sulphonyl group in aqueous solution at a mercury electrode is reported. At pH < 10 the compound was reduced in a single well-defined step. Reduction of the nitro group involving a preceding protonation step was postulated. Two reduction steps are present at higher pH (pH > 11). Controlled potential electrolysis confirms that the reduction of the nitro group in a four-electron step to N-phenyl-4-hydroxylamine sulphonamide is always the preponderant process. ©1997 Soc. Bras. Química. | en |
dc.format.extent | 223-227 | - |
dc.language.iso | eng | - |
dc.source | Scopus | - |
dc.subject | Amine improtection | - |
dc.subject | Cathodic cleavage | - |
dc.subject | Nitrobenzenesulphonamide | - |
dc.title | Electrochemical behavior of a nitrobenzenesulfonyl derivative of aniline in aqueous solution | en |
dc.type | outro | - |
dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
dc.contributor.institution | Universidade de São Paulo (USP) | - |
dc.description.affiliation | Depto. de Quim. Analítica Institute de Química UNESP, C.P.355, 14800-900 Araraquara - SP | - |
dc.description.affiliation | Departamento de Química Faculdade de Filos., Cie. e Letras USP, C.P. 3900, 14040-901 Ribeirão Preta - SP | - |
dc.description.affiliationUnesp | Depto. de Quim. Analítica Institute de Química UNESP, C.P.355, 14800-900 Araraquara - SP | - |
dc.identifier.doi | 10.1590/S0103-50531997000300007 | - |
dc.identifier.scielo | S0103-50531997000300007 | - |
dc.identifier.wos | WOS:A1997XG43500007 | - |
dc.rights.accessRights | Acesso aberto | - |
dc.identifier.file | 2-s2.0-0031350991.pdf | - |
dc.relation.ispartof | Journal of the Brazilian Chemical Society | - |
dc.identifier.scopus | 2-s2.0-0031350991 | - |
Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp |
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