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http://acervodigital.unesp.br/handle/11449/66026Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | De Andrade Leite, Sergio R. | - |
| dc.contributor.author | Couto Dos Santos, Marco A. | - |
| dc.contributor.author | Carubelli, Célia R. | - |
| dc.contributor.author | Galindo Massabni, Ana M. | - |
| dc.date.accessioned | 2014-05-27T11:19:51Z | - |
| dc.date.accessioned | 2016-10-25T18:16:09Z | - |
| dc.date.available | 2014-05-27T11:19:51Z | - |
| dc.date.available | 2016-10-25T18:16:09Z | - |
| dc.date.issued | 1999-12-01 | - |
| dc.identifier | http://dx.doi.org/10.1016/S1386-1425(98)00274-1 | - |
| dc.identifier.citation | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, v. 55, n. 6, p. 1185-1191, 1999. | - |
| dc.identifier.issn | 1386-1425 | - |
| dc.identifier.uri | http://hdl.handle.net/11449/66026 | - |
| dc.identifier.uri | http://acervodigital.unesp.br/handle/11449/66026 | - |
| dc.description.abstract | Chemical characterization as well as spectroscopical study of the L-histidine-europium(III) complex were developed both experimental and theoretically. Molecular mechanics (MM) simulation was performed in order to have indication of the compound structure and the Eu 3+ chemical environment. The Simple Overlap Model (SOM) was applied to predict spectroscopic quantities as 5D 0→ 7F 0/ 5D 0→ 7F 2 intensity ratio, 5D 0→ 7F 1 transition splitting and the intensity Ω λ parameters (λ = 2 and 4). Satisfactory results are obtained with 0.1 and 2/3 as the effective charges of the nitrogen (gN) and oxygen (gO) respectively, and their polarizabilities (α) depend on the distance. © 1999 Elsevier Science B.V. All rights reserved. | en |
| dc.format.extent | 1185-1191 | - |
| dc.language.iso | eng | - |
| dc.source | Scopus | - |
| dc.subject | Europium | - |
| dc.subject | Histidine | - |
| dc.subject | Luminescence | - |
| dc.subject | Molecular mechanics | - |
| dc.subject | Simple overlap model | - |
| dc.subject | Spectroscopy | - |
| dc.title | L-Histidine-europium(III) complex: A spectroscopical study | en |
| dc.type | outro | - |
| dc.contributor.institution | Universidade Estadual Paulista (UNESP) | - |
| dc.contributor.institution | Universidade Estadual de Ponta Grossa (UEPG) | - |
| dc.description.affiliation | Universidade Estadual Paulista Institute de Qulmica, Caixa postal 355, 14801-970 Araraquara-SP | - |
| dc.description.affiliation | Univ. Estadual de Ponta Grossa, Ponta Grossa-PR | - |
| dc.description.affiliationUnesp | Universidade Estadual Paulista Institute de Qulmica, Caixa postal 355, 14801-970 Araraquara-SP | - |
| dc.identifier.doi | 10.1016/S1386-1425(98)00274-1 | - |
| dc.identifier.wos | WOS:000080050400005 | - |
| dc.rights.accessRights | Acesso restrito | - |
| dc.relation.ispartof | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | - |
| dc.identifier.scopus | 2-s2.0-9344226131 | - |
| Appears in Collections: | Artigos, TCCs, Teses e Dissertações da Unesp | |
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