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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/75444
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dc.contributor.authorMacHado, Angelo H. L.-
dc.contributor.authorMilagre, Humberto M. S.-
dc.contributor.authorEberlin, Livia S.-
dc.contributor.authorSabino, Adão A.-
dc.contributor.authorCorreia, Carlos Roque D.-
dc.contributor.authorEberlin, Marcos N.-
dc.date.accessioned2014-05-27T11:29:32Z-
dc.date.accessioned2016-10-25T18:48:39Z-
dc.date.available2014-05-27T11:29:32Z-
dc.date.available2016-10-25T18:48:39Z-
dc.date.issued2013-05-28-
dc.identifierhttp://dx.doi.org/10.1039/c3ob40142a-
dc.identifier.citationOrganic and Biomolecular Chemistry, v. 11, n. 20, p. 3277-3281, 2013.-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/11449/75444-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/75444-
dc.description.abstractThe dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. © 2013 The Royal Society of Chemistry.en
dc.format.extent3277-3281-
dc.language.isoeng-
dc.sourceScopus-
dc.subjectCatalytic cycles-
dc.subjectHeck-matsuda reactions-
dc.subjectPalladium intermediates-
dc.subjectPalladium species-
dc.subjectTransient complexes-
dc.subjectWacker-type reactions-
dc.subjectChemistry-
dc.subjectPositive ions-
dc.subjectReaction intermediates-
dc.titleDba-free palladium intermediates of the Heck-Matsuda reactionen
dc.typeoutro-
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade Federal de Minas Gerais (UFMG)-
dc.description.affiliationChemistry Institute University of Campinas - UNICAMP, Campinas-
dc.description.affiliationThomson Laboratory University of Campinas - UNICAMP, Campinas-
dc.description.affiliationInstitute of Biosciences Universidade Estadual Paulista - UNESP, Rio-Claro-
dc.description.affiliationDepartment of Chemistry Federal University of Minas Gerais - UFMG, Belo Horizonte-
dc.description.affiliationUnespInstitute of Biosciences Universidade Estadual Paulista - UNESP, Rio-Claro-
dc.identifier.doi10.1039/c3ob40142a-
dc.identifier.wosWOS:000318306400002-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofOrganic and Biomolecular Chemistry-
dc.identifier.scopus2-s2.0-84877257398-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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