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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/76837
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dc.contributor.authorPaiva, Isabela L.-
dc.contributor.authorDe Carvalho, Gustavo S.G.-
dc.contributor.authorDa Silva, Adilson D.-
dc.contributor.authorCorbi, Pedro P.-
dc.contributor.authorBergamini, Fernando R.G.-
dc.contributor.authorFormiga, André L.B.-
dc.contributor.authorDiniz, Renata-
dc.contributor.authorDo Carmo, Weberton R.-
dc.contributor.authorLeite, Clarice Q.F.-
dc.contributor.authorPavan, Fernando Rogério-
dc.contributor.authorCuin, Alexandre-
dc.date.accessioned2014-05-27T11:30:51Z-
dc.date.accessioned2016-10-25T18:54:57Z-
dc.date.available2014-05-27T11:30:51Z-
dc.date.available2016-10-25T18:54:57Z-
dc.date.issued2013-10-14-
dc.identifierhttp://dx.doi.org/10.1016/j.poly.2013.06.031-
dc.identifier.citationPolyhedron, v. 62, p. 104-109.-
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/11449/76837-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/76837-
dc.description.abstractSynthesis, structural and spectroscopic characterizations, molecular modeling and antimycobacterial assays of new silver(I) complexes with two Schiff bases - MBDA and MBDB - are reported. The complexes [Ag(MBDA) 2]NO3, or AgMBDA, and [Ag(MBDB)NO3] or AgMBDB, were obtained by the reaction of the respective ligands with silver(I) nitrate in methanol. The Schiff bases were previously obtained by mixing ethylenediamine or 1,3-diaminopropane with p-anisaldehyde. The characterizations of the complexes were based on elemental (C, H and N) and thermal (TG-DTA) analyses and 13C and 1H NMR and FT-IR spectroscopic measurements, as well as X-ray structure determination for AgMBDA. Spectroscopic data predicted by DFT calculations are in agreement with the experimental data for the AgMBDA complex. The AgMBDA complex has a monomeric structure with a molar proportion 1:2 Ag/ligand, while AgMBDB presents a 1:1 proportion. The complexes AgMBDA and AgMBDB showed to be more effective against Mycobacterium tuberculosis than antibacterial agent silver sulfadiazine - SSD. © 2013 Elsevier Ltd. All rights reserved.en
dc.format.extent104-109-
dc.language.isoeng-
dc.sourceScopus-
dc.subjectAnisaldehyde-
dc.subjectMycobacterium-
dc.subjectSchiff bases-
dc.subjectSilver-
dc.subjectTuberculosis-
dc.titleSilver(I) complexes with symmetrical Schiff bases: Synthesis, structural characterization, DFT studies and antimycobacterial assaysen
dc.typeoutro-
dc.contributor.institutionUniversidade Federal de Juiz de Fora (UFJF)-
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.description.affiliationDepartamento de Química Instituto de Ciências Exatas UFJF, 36036-900 Juiz de Fora, MG-
dc.description.affiliationInstituto de Química Universidade de Campinas UNICAMP, 13083-970 Campinas, SP-
dc.description.affiliationDepartamento Ciências Biológicas Faculdade de Ciências Farmacêuticas UNESP, 14800-900 Araraquara, SP-
dc.description.affiliationUnespDepartamento Ciências Biológicas Faculdade de Ciências Farmacêuticas UNESP, 14800-900 Araraquara, SP-
dc.identifier.doi10.1016/j.poly.2013.06.031-
dc.identifier.wosWOS:000324226200013-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofPolyhedron-
dc.identifier.scopus2-s2.0-84885133308-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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