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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/76881
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dc.contributor.authorVaz, Boniek G.-
dc.contributor.authorMilagre, Cintia Duarte de Freitas-
dc.contributor.authorEberlin, Marcos N.-
dc.contributor.authorMilagre, Humberto Márcio Santos-
dc.date.accessioned2014-05-27T11:30:52Z-
dc.date.accessioned2016-10-25T18:55:03Z-
dc.date.available2014-05-27T11:30:52Z-
dc.date.available2016-10-25T18:55:03Z-
dc.date.issued2013-10-21-
dc.identifierhttp://dx.doi.org/10.1039/c3ob41318g-
dc.identifier.citationOrganic and Biomolecular Chemistry, v. 11, n. 39, p. 6695-6698, 2013.-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/11449/76881-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/76881-
dc.description.abstractEvidence is provided for the inner-sphere mechanism with actual metal coordination of the racemic amine in the crucial hydrogen transfer step promoted by Shvo's catalyst of the chemoenzymatic dynamic kinetic resolution (DKR) of amines. Key intermediates involved in this H-transfer step were intercepted and continuously monitored by electrospray ionization mass spectrometry (ESI-MS) and characterized by their dissociation chemistries via ESI-MS/MS. © 2013 The Royal Society of Chemistry.en
dc.format.extent6695-6698-
dc.language.isoeng-
dc.sourceScopus-
dc.subjectDissociation chemistry-
dc.subjectDynamic kinetic resolution-
dc.subjectElectrospray ionization mass spectrometry-
dc.subjectHydrogen transfer-
dc.subjectInnersphere mechanism-
dc.subjectMetal coordination-
dc.subjectAmines-
dc.subjectCatalysts-
dc.subjectMass spectrometry-
dc.subjectDynamics-
dc.titleShvo's catalyst in chemoenzymatic dynamic kinetic resolution of amines-inner or outer sphere mechanism?en
dc.typeoutro-
dc.contributor.institutionUniversidade Federal de Goiás (UFG)-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionUniversidade Estadual de Campinas (UNICAMP)-
dc.description.affiliationInstitute of Chemistry Federal University of Goiás Campus Samambaia, Caixa Postal 131, Goiânia Goiás CEP 74001-970-
dc.description.affiliationDepartment of Organic Chemistry Institute of Chemistry Univ. Estadual Paulista UNESP, 14800-060 Araraquara SP-
dc.description.affiliationThoMSon Mass Spectrometry Laboratory Institute of Chemistry University of Campinas UNICAMP, 13084-971 Campinas SP-
dc.description.affiliationUnespDepartment of Organic Chemistry Institute of Chemistry Univ. Estadual Paulista UNESP, 14800-060 Araraquara SP-
dc.identifier.doi10.1039/c3ob41318g-
dc.identifier.wosWOS:000325119600006-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofOrganic and Biomolecular Chemistry-
dc.identifier.scopus2-s2.0-84884472099-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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