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Please use this identifier to cite or link to this item: http://acervodigital.unesp.br/handle/11449/76014
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dc.contributor.authorPinto, Leandro M. C.-
dc.contributor.authorSpohr, Eckhard-
dc.contributor.authorQuaino, Paola-
dc.contributor.authorSantos, Elizabeth-
dc.contributor.authorSchmickler, Wolfgang-
dc.date.accessioned2014-05-27T11:29:58Z-
dc.date.accessioned2016-10-25T18:51:33Z-
dc.date.available2014-05-27T11:29:58Z-
dc.date.available2016-10-25T18:51:33Z-
dc.date.issued2013-07-22-
dc.identifierhttp://dx.doi.org/10.1002/anie.201301998-
dc.identifier.citationAngewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.-
dc.identifier.issn1433-7851-
dc.identifier.issn1521-3773-
dc.identifier.urihttp://hdl.handle.net/11449/76014-
dc.identifier.urihttp://acervodigital.unesp.br/handle/11449/76014-
dc.description.abstractA perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.description.sponsorshipDeutsche Forschungsgemeinschaft (DFG)-
dc.format.extent7883-7885-
dc.language.isoeng-
dc.sourceScopus-
dc.subjectcorrosion-
dc.subjectmetal deposition-
dc.subjecttheoretical electrochemistry-
dc.subjectElectrochemical reactions-
dc.subjectMD simulation-
dc.subjectMetal deposition-
dc.subjectPerfect matches-
dc.subjectSilver deposition-
dc.subjectSolvation energy-
dc.subjectStrong interaction-
dc.subjectCatalysis-
dc.subjectChemistry-
dc.subjectCorrosion-
dc.subjectDeposition-
dc.titleWhy silver deposition is so fast: Solving the enigma of metal depositionen
dc.typeoutro-
dc.contributor.institutionUlm University-
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)-
dc.contributor.institutionLehrstuhl für Theoretische Chemie-
dc.contributor.institutionUniversidad Nacional Del Litoral-
dc.contributor.institutionUniversidad Nacional de Cõrdoba-
dc.description.affiliationInstitute of Theoretical Chemistry Ulm University, 89069 Ulm-
dc.description.affiliationFaculdade de Ciências Univ Estadual Paulista UNESP, 17.033-360 Bauru-SP-
dc.description.affiliationUniversität Duisburg-Essen Lehrstuhl für Theoretische Chemie, 45134 Essen-
dc.description.affiliationPRELINE Universidad Nacional Del Litoral, Santa Fe-
dc.description.affiliationFaculdad de Matemática, Astronomía y Física IFEG-CONICET Universidad Nacional de Cõrdoba, Cõrdoba-
dc.description.affiliationUnespFaculdade de Ciências Univ Estadual Paulista UNESP, 17.033-360 Bauru-SP-
dc.description.sponsorshipIdDFG: Schm 344/34-1,2-
dc.description.sponsorshipIdDFG: FOR 1376-
dc.identifier.doi10.1002/anie.201301998-
dc.identifier.wosWOS:000321896800057-
dc.rights.accessRightsAcesso restrito-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.identifier.scopus2-s2.0-84880359340-
Appears in Collections:Artigos, TCCs, Teses e Dissertações da Unesp

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